Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster.
نویسندگان
چکیده
A polyoxotetradecamolybdate cluster [Mo(14)O(38)(OAc)(6)](2-), which has a lacunary core of the Wells-Dawson structure, is isolated by the reduction of [Mo(6)O(19)](2-). The Mo(14) core is comprised of a mixed valence of [Mo(V)(4)Mo(VI)(10)], exhibiting multi-step reversible redox processes that experience both oxidation and reduction.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 45 شماره
صفحات -
تاریخ انتشار 2011